Okay, as in Jeopardy, I will give you the answers, you have to provide the question. Please be sure it is in the form of a question:
1. Ace, Prof, Rocky and Red.
2. The Gloom Room A-Go-Go.
3. The Green Goblin and Captain Stacy.
4. Edward Nigma.
5. The Super-Adaptoid, Amazo and the Composite Superman.